Apple Cider Vinegar Shampoo vs Smooth Proof Shampoo: which is safer?

Aveeno Apple Cider Vinegar Shampoo is our pick, better on PFAS and on the overall hazard picture.

Our pick

Aveeno Apple Cider Vinegar Shampoo

Aveeno

Apple Cider Vinegar Shampoo

PFAS grade

Excellent 75/100

Overall grade

Good 63/100

Verdict

Buy

Hazard flags

⚑ 3

Material

aqueous liquid shampoo (typical surfactants, conditioning agents, water)

Confidence

82%

PossibleSurfactant irritation (skin/eye contact)

PossibleFragrance allergens

PossibleMicrobial contamination (post-purchase)

Biolage Smooth Proof Shampoo

Biolage

Smooth Proof Shampoo

PFAS grade

Excellent 75/100

Overall grade

Good 57/100

Verdict

Buy

Hazard flags

⚑ 3

Material

aqueous liquid shampoo formulation

Confidence

72%

PossibleFragrance allergens and sensitizers

PossibleFormaldehyde-releasing preservatives

ReportedEye and mucous membrane irritation

Where these two actually differ

  • We flag Surfactant irritation (skin/eye contact), Fragrance allergens and Microbial contamination (post-purchase) on the Aveeno and not on the Biolage.
  • We flag Fragrance allergens and sensitizers, Formaldehyde-releasing preservatives and Eye and mucous membrane irritation on the Biolage and not on the Aveeno.
  • The Aveeno is aqueous liquid shampoo (typical surfactants, conditioning agents, water) where the Biolage is aqueous liquid shampoo formulation, which is most of the difference in these two grades.
  • These two are level, close enough that price and fit should decide it rather than our grade.

Both products run through the same public rubric, which covers materials, coatings, brand disclosure, lab findings, and recalls, plus a beyond-PFAS hazard analysis. Grades are model-based estimates, not lab tests. How grades work →

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