Waterproof Hiking Socks, ranked by PFAS safety

15 products graded from Bad to Excellent, safest first. None grade Good or better yet, so we show the full ranking and the least-concerning options first.

By material:Wool

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The best non-toxic waterproof hiking socks, ranked safest first

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Graded and flagged Poor and Bad, we’d swap these

Smartwool Men's Mountaineer Classic Edition Maximum Cushion Crew Socks

Smartwool

Men's Mountaineer Classic Edition Maximum Cushion Crew Socks

Merino wool blend (primary natural fiber)

PFAS Grade65Good
Good

Lower PFAS concern. Natural wool fiber with no waterproofing treatment flagged. No explicit PFAS disclosure.

Risky category by default

Smartwool Men's Hike Full Cushion Crew Socks

Smartwool

Men's Hike Full Cushion Crew Socks

Merino wool blend (merino wool, nylon, elastane)

PFAS Grade65Good
Good

Lower PFAS concern. Natural fiber socks unlikely to need water-repellent coating. Smartwool's lack of disclosure leaves room for uncertainty.

Risky category by default

Smartwool Men's Hike Classic Edition Full Cushion Crew Socks

Smartwool

Men's Hike Classic Edition Full Cushion Crew Socks

Merino wool blend (primary fiber); no reported water-repellent coating (water-repellent coating) or stain treatment disclosed

PFAS Grade65Good
Good

Lower PFAS concern. Plain wool socks with no disclosed treatments, but verify fiber content if it matters.

Risky category by default

Darn Tough Men's Spaced Out Micro Crew Lightweight Hiking Socks

Darn Tough

Men's Spaced Out Micro Crew Lightweight Hiking Socks

Merino wool blend, nylon, spandex

PFAS Grade65Good
Good

Lower PFAS concern for untreated wool socks.

Risky category by default

Darn Tough Men's Hiker Encounter 2-Pack

Darn Tough

Men's Hiker Encounter 2-Pack

Merino wool blend, no water-repellent treatment applied

PFAS Grade65Good
Good

Lower PFAS concern. Wool hiking socks without water-repellent coating treatment are a safer choice.

Risky category by default

Darn Tough Men's Weird and Wild Hiking 2-Pack

Darn Tough

Men's Weird and Wild Hiking 2-Pack

merino wool blend, nylon

PFAS Grade65Good
Good

Lower concern. Natural-fiber hiking socks unlikely to require PFAS. No public disclosure from Darn Tough.

Risky category by default

Bridgedale Lightweight Boot Socks

Bridgedale

Lightweight Boot Socks

Merino wool blend, acrylic, polyamide

PFAS Grade65Good
Good

Lower concern. Natural fiber blend socks with no known water-repellent coating or performance coatings flagged.

Risky category by default

Merrell Moab Hiker Low Cut Sock

Merrell

Moab Hiker Low Cut Sock

merino wool blend, synthetic fibers

PFAS Grade65Good
Good

Lower PFAS risk; standard sock with no waterproofing claims.

Risky category by default

Merrell Premium Wool Trail Low Cut Sock

Merrell

Premium Wool Trail Low Cut Sock

Merino wool blend, no known water-repellent coating treatment disclosed

PFAS Grade65Good
Good

Lower risk but Merrell's silence on water-repellent coating treatment leaves uncertainty.

Risky category by default

Merrell Premium Wool Trail Crew Socks

Merrell

Premium Wool Trail Crew Socks

Merino/premium wool blend, no water-resistant coating mentioned

PFAS Grade65Good
Good

Lower PFAS risk, wool socks without disclosed treatments carry minimal concern.

Risky category by default

The North Face Hiking Crew Socks

The North Face

Hiking Crew Socks

Merino wool blend / synthetic fibers (polyester, nylon)

PFAS Grade65Good
Good

Lower concern, standard socks aren't typical PFAS application areas, but no transparency from brand.

Risky category by default

Bridgedale Men's StormSock Waterproof Heavyweight Boot Socks

Bridgedale

Men's StormSock Waterproof Heavyweight Boot Socks

Merino wool blend with water-repellent coating (water-repellent coating) finish

PFAS Grade20Bad
Overall Grade0Bad
💨

Formaldehyde / VOCs

Limited concern

70
🎨

Heavy metals

Limited concern

70
🫧

Degradation and microfiber shedding during washing

High concern

20
🏷️

PFAS

Moderate concern

45

High PFAS risk. Waterproofing likely contains PFAS. No public disclosure or testing available.

Waterproof or stain-proof treatment

Bridgedale StormSock Midweight Knee

Bridgedale

StormSock Midweight Knee

Wool blend with water-repellent coating finish

PFAS Grade20Bad
Overall Grade16Bad

water-repellent coating degradation and leachables

Limited concern

70

Lower concern choice, but Bridgedale's water-repellent coating treatment remains undisclosed.

Waterproof or stain-proof treatment

Merrell Moab Hiker Crew Hiking Socks

Merrell

Moab Hiker Crew Hiking Socks

Merino wool/synthetic blend with water-repellent coating treatment

PFAS Grade20Bad
Overall Grade12Bad
🍳

water-repellent coating chemistry (fluorinated or non-fluorinated, unspecified)

Limited concern

70
⚠️

Contact dermatitis or sensitization from residual dyes or finishes

Limited concern

70

Lower concern for most wearers, but water-repellent coating treatment chemicals unspecified.

Waterproof or stain-proof treatment

Merrell Moab Hiking Quarter Socks

Merrell

Moab Hiking Quarter Socks

merino wool blend with water-repellent coating treatment (likely fluorocarbon-based)

PFAS Grade20Bad
Overall Grade12Bad
♾️

PFAS

Limited concern

70
🫧

Synthetic fiber shedding (microfibers)

Limited concern

70

Avoid until Merrell discloses whether water-repellent coating uses PFAS chemicals.

Waterproof or stain-proof treatment

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